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Publications

  1. Q.A. Akkerman, B. Martin-Garcia, J. Buha, G. Almeida, S. Toso, S. Marras, F. Bonaccorso, U. Petralanda, I. Infante, and L. Manna, Ultrathin Orthorhombic PbS Nanosheets. Chemistry of Materials, vol. 31, p. 8145-8153, 2019, doi: 10.1021/acs.chemmater.9b02914.
  2. Q.A. Akkerman, D. Meggiolaro, Z.Y. Dang, F. De Angelis, and L. Manna, Fluorescent Alloy CsPbxMn1-x,I-3 Perovskite Nanocrystals with High Structural and Optica Stability. Acs Energy Letters, vol. 2, p. 2183-2186, 2017, doi: 10.1021/acsenergylett.7b00707.
  3. Q.A. Akkerman, S. Park, E. Radicchi, F. Nunzi, E. Mosconi, F. De Angelis, R. Brescia, P. Rastogi, M. Prato, and L. Manna, Nearly Monodisperse Insulator Cs4PbX6 (X = Cl, Br, I) Nanocrystals, Their Mixed Halide Compositions, and Their Transformation into CsPbX3 Nanocrystals. Nano Letters, vol. 17, p. 1924-1930, 2017, doi: 10.1021/acs.nanolett.6b05262.
  4. N.C. Anderson, P.E. Chen, A.K. Buckley, J. De Roo, and J.S. Owen, Stereoelectronic Effects on the Binding of Neutral Lewis Bases to CdSe Nanocrystals. Journal of the American Chemical Society, vol. 140, p. 7199-7205, 2018, doi: 10.1021/jacs.8b02927.
  5. G. Bertoni, Q. Ramasse, R. Brescia, L. De Trizio, F. De Donato, and L. Manna, Direct Quantification of Cu Vacancies and Spatial Localization of Surface Plasmon Resonances in Copper Phosphide Nanocrystals. Acs Materials Letters, vol. 1, p. 665-670, 2019, doi: 10.1021/acsmaterialslett.9b00412.
  6. J. Billet, W. Dujardin, K. De Keukeleere, K. De Buysser, J. De Roo, and I. Van Driessche, Size Tunable Synthesis and Surface Chemistry of Metastable TiO2-Bronze Nanocrystals. Chemistry of Materials, vol. 30, p. 4298-4306, 2018, doi: 10.1021/acs.chemmater.8b01296.
  7. S. Bisschop, P. Geiregat, T. Aubert, and Z. Hens, The Impact of Core/Shell Sizes on the Optical Gain Characteristics of CdSe/CdS Quantum Dots. Acs Nano, vol. 12, p. 9011-9021, 2018, doi: 10.1021/acsnano.8b02493.
  8. B.J. Bohn, T. Simon, M. Gramlich, A.F. Richter, L. Polavarapu, A.S. Urban, and J. Feldmann, Dephasing and Quantum Beating of Excitons in Methylammonium Lead Iodide Perovskite Nanoplatelets. Acs Photonics, vol. 5, p. 648-654, 2018, doi: 10.1021/acsphotonics.7b01292.
  9. B.J. Bohn, Y. Tong, M. Gramlich, M.L. Lai, M. Doblinger, K. Wang, R.L.Z. Hoye, P. Muller-Buschbaum, S.D. Stranks, A.S. Urban, L. Polavarapu, and J. Feldmann, Boosting Tunable Blue Luminescence of Halide Perovskite Nanoplatelets through Postsynthetic Surface Trap Repair. Nano Letters, vol. 18, p. 5231-5238, 2018, doi: 10.1021/acs.nanolett.8b02190.
  10. A. Brodu, M.V. Ballottin, J. Buhot, D. Dupont, M. Tessier, Z. Hens, F.T. Rabouw, P.C.M. Christianen, C.D. Donega, and D. Vanmaekelbergh, Exciton-phonon coupling in InP quantum dots with ZnS and (Zn, Cd) Se shells. Physical Review B, vol. 101, 2020, doi: 10.1103/PhysRevB.101.125413.
  11. A. Brodu, M.V. Ballottin, J. Buhot, E.J. van Harten, D. Dupont, A. La Porta, P.T. Prins, M.D. Tessier, M.A.M. Versteegh, V. Zwiller, S. Bals, Z. Hens, F.T. Rabouw, P.C.M. Christianen, C.D. Donega, and D. Vanmaekelbergh, Exciton Fine Structure and Lattice Dynamics in InP/ZnSe Core/Shell Quantum Dots. Acs Photonics, vol. 5, p. 3353-3362, 2018, doi: 10.1021/acsphotonics.8b00615.
  12. V. Caligiuri, G. Biffi, M. Palei, B. Martin-Garcia, R.D. Pothuraju, Y. Bretonniere, and R. Krahne, Angle and Polarization Selective Spontaneous Emission in Dye-Doped Metal/Insulator/Metal Nanocavities. Advanced Optical Materials, vol. 8, 2020, doi: 10.1002/adom.201901215. 8
  13. V. Caligiuri, M. Palei, G. Biffi, S. Artyukhin, and R. Krahne, A Semi-Classical View on Epsilon-Near-Zero Resonant Tunneling Modes in Metal/Insulator/Metal Nanocavities. Nano Letters, vol. 19, p. 3151-3160, 2019, doi: 10.1021/acs.nanolett.9b00564.
  14. V. Caligiuri, M. Palei, M. Imran, L. Manna, and R. Krahne, Planar Double-Epsilon-Near-Zero Cavities for Spontaneous Emission and Purcell Effect Enhancement. Acs Photonics, vol. 5, p. 2287-2294, 2018, doi: 10.1021/acsphotonics.8b00121.
  15. V. Caligiuri, M. Patel, G. Biffi, and R. Krahne, Hybridization of epsilon-near-zero modes via resonant tunneling in layered metal-insulator double nanocavities. Nanophotonics, vol. 8, p. 1505-1512, 2019, doi: 10.1515/nanoph-2019-0054.
  16. M.P. Campos, M.P. Hendricks, A.N. Beecher, W. Wslravens, R.A. Swain, G.T. Cleyeland, Z. Hens, M.Y. Sfeir, and J.S. Owen, A Library of Selenourea Precursors to PbSe Nanocrystals with Size Distributions near the Homogeneous Limit. Journal of the American Chemical Society, vol. 139, p. 2296-2305, 2017, doi: 10.1021/jacs.6b11021.
  17. A. Castelli, B. Dhanabalan, A. Polovitsyn, V. Caligiuri, F. Di Stasio, A. Scarpellini, R. Brescia, M. Palei, B. Martin-Garcia, M. Prato, L. Manna, I. Moreels, R. Krahne, and M.P. Arciniegas, Core/Shell CdSe/CdS Bone-Shaped Nanocrystals with a Thick and Anisotropic Shell as Optical Emitters. Advanced Optical Materials, vol. 8, 2020, doi: 10.1002/adom.201901463.
  18. K. De Keukeleere, S. Coucke, E. De Canck, P. Van Der Voort, F. Delpech, Y. Coppel, Z. Hens, I. Van Driessche, J.S. Owen, and J. De Roo, Stabilization of Colloidal Ti, Zr, and Hf Oxide Nanocrystals by Protonated Tri-n-octylphosphine Oxide (TOPO) and Its Decomposition Products. Chemistry of Materials, vol. 29, p. 10233-10242, 2017, doi: 10.1021/acs.chemmater.7b04580.
  19. J. De Roo, Z.Y. Huang, N.J. Schuster, L.S. Hamachi, D.N. Congreve, Z.H. Xu, P. Xia, D.A. Fishman, T.Q. Lian, J.S. Owen, and M.L. Tang, Anthracene Diphosphate Ligands for CdSe Quantum Dots; Molecular Design for Efficient Upconversion. Chemistry of Materials, vol. 32, p. 1461-1466, 2020, doi: 10.1021/acs.chemmater.9b04294.
  20. J. De Roo, N. Yazdani, E. Drijvers, A. Lauria, J. Maes, J.S. Owen, I. Van Driessche, M. Niederberger, V. Wood, J.C. Martins, I. Infante, and Z. Hens, Probing Solvent-Ligand Interactions in Colloidal Nanocrystals by the NMR Line Broadening. Chemistry of Materials, vol. 30, p. 5485-5492, 2018, doi: 10.1021/acs.chemmater.8b02523.
  21. J. De Roo, Z.M. Zhou, J.Y. Wang, L. Deblock, A.J. Crosby, J.S. Owen, and S.S. Nonnenmann, Synthesis of Phosphonic Acid Ligands for Nanocrystal Surface Functionalization and Solution Processed Memristors. Chemistry of Materials, vol. 30, p. 8034-8039, 2018, doi: 10.1021/acs.chemmater.8b03768.
  22. B. Dhanabalan, A. Castelli, M. Palei, D. Spirito, L. Manna, R. Krahne, and M. Arciniegas, Simple fabrication of layered halide perovskite platelets and enhanced photoluminescence from mechanically exfoliated flakes. Nanoscale, vol. 11, p. 8334-8342, 2019, doi: 10.1039/c9nr00638a.
  23. F. Di Stasio, M. Imran, Q.A. Akkerman, M. Prato, L. Manna, and R. Krahne, Reversible Concentration-Dependent Photoluminescence Quenching and Change of Emission Color in CsPbBr3 Nanowires and Nanoplatelets. Journal of Physical Chemistry Letters, vol. 8, p. 2725-2729, 2017, doi: 10.1021/acs.jpclett.7b01305.
  24. E. Drijvers, J. De Roo, J.C. Martins, I. Infante, and Z. Hens, Ligand Displacement Exposes Binding Site Heterogeneity on CdSe Nanocrystal Surfaces. Chemistry of Materials, vol. 30, p. 1178-1186, 2018, doi: 10.1021/acs.chemmater.7b05362.
  25. E. Drijvers, J. Liu, A. Harizaj, U. Wiesner, K. Braeckmans, Z. Hens, and T. Aubert, Efficient Endocytosis of Inorganic Nanoparticles with Zwitterionic Surface Functionalization. Acs Applied Materials & Interfaces, vol. 11, p. 38475-38482, 2019, doi: 10.1021/acsami.9b12398.
  26. S. Ghosh and L. Manna, The Many "Facets" of Halide Ions in the Chemistry of Colloidal Inorganic Nanocrystals. Chemical Reviews, vol. 118, p. 7804-7864, 2018, doi: 10.1021/acs.chemrev.8b00158. 9
  27. V. Grigel, L.K. Sagar, K. De Nolf, Q. Zhao, A. Vantomme, J. De Roo, I. Infante, and Z. Hens, The Surface Chemistry of Colloidal HgSe Nanocrystals, toward Stoichiometric Quantum Dots by Design. Chemistry of Materials, vol. 30, p. 7637-7647, 2018, doi: 10.1021/acs.chemmater.8b02908.
  28. L.S. Hamachi, I.J.L. Plante, A.C. Coryell, J. De Roo, and J.S. Owen, Kinetic Control over CdS Nanocrystal Nucleation Using a Library of Thiocarbonates, Thiocarbamates, and Thioureas. Chemistry of Materials, vol. 29, p. 8711-8719, 2017, doi: 10.1021/acs.chemmater.7b02861.
  29. L.S. Hamachi, H.R. Yang, I. Jen-La Plante, N. Saenz, K. Qian, M.P. Campos, G.T. Cleveland, I. Rreza, A. Oza, W. Walravens, E.M. Chan, Z. Hens, A.C. Crowther, and J.S. Owen, Precursor reaction kinetics control compositional grading and size of CdSe1-xSx nanocrystal heterostructures. Chemical Science, vol. 10, p. 6539-6552, 2019, doi: 10.1039/c9sc00989b.
  30. V.A. Hintermayr, C. Lampe, M. Low, J. Roemer, W. Vanderlinden, M. Gramlich, A.X. Bohm, C. Sattler, B. Nickel, T. Lohmuller, and A.S. Urban, Polymer Nanoreactors Shield Perovskite Nanocrystals from Degradation. Nano Letters, vol. 19, p. 4928-4933, 2019, doi: 10.1021/acs.nanolett.9b00982.
  31. V.A. Hintermayr, L. Polavarapu, A.S. Urban, and J. Feldmann, Accelerated Carrier Relaxation through Reduced Coulomb Screening in Two-Dimensional Halide Perovskite Nanoplatelets. Acs Nano, vol. 12, p. 10151-10158, 2018, doi: 10.1021/acsnano.8b05029.
  32. P. Ijaz, M. Imran, M.M. Soares, H.C.N. Tolentino, B. Martin-Garcia, C. Giannini, I. Moreels, L. Manna, and R. Krahne, Composition-, Size-, and Surface Functionalization-Dependent Optical Properties of Lead Bromide Perovskite Nanocrystals. Journal of Physical Chemistry Letters, vol. 11, p. 2079-2085, 2020, doi: 10.1021/acs.jpclett.0c00266.
  33. R. Kaiukov, G. Almeida, S. Marras, Z.Y. Dang, D. Baranov, U. Petralanda, I. Infante, E. Mugnaioli, A. Griesi, L. De Trizio, M. Gemmi, and L. Manna, Cs3Cu4In2Cl13 Nanocrystals: A Perovskite-Related Structure with Inorganic Clusters at A Sites. Inorganic Chemistry, vol. 59, p. 548-554, 2020, doi: 10.1021/acs.inorgchem.9b02834.
  34. M.L. Lin, M. Miscuglio, A. Polovitsyn, Y.C. Leng, B. Martin-Garcia, I. Moreels, P.H. Tan, and R. Krahne, Giant-Shell CdSe/CdS Nanocrystals: Exciton Coupling to Shell Phonons Investigated by Resonant Raman Spectroscopy. Journal of Physical Chemistry Letters, vol. 10, p. 399-405, 2019, doi: 10.1021/acs.jpclett.8b03211.
  35. F. Locardi, E. Sartori, J. Buha, J. Zito, M. Prato, V. Pinchetti, M.L. Zaffalon, M. Ferretti, S. Brovelli, I. Infante, L. De Trizio, and L. Manna, Emissive Bi-Doped Double Perovskite Cs2Ag1-xNaxInCl6 Nanocrystals. Acs Energy Letters, vol. 4, p. 1976-1982, 2019, doi: 10.1021/acsenergylett.9b01274.
  36. M. Lorenzon, L. Sortino, Q. Akkerman, S. Accornero, J. Pedrini, M. Prato, V. Pinchetti, F. Meinardi, L. Manna, and S. Brovelli, Role of Nonradiative Defects and Environmental Oxygen on Exciton Recombination Processes in CsPbBr3 Perovskite Nanocrystals. Nano Letters, vol. 17, p. 3844-3853, 2017, doi: 10.1021/acs.nanolett.7b01253.
  37. . Ma, Y.Y. Gong, T. Aubert, M.Z. Turker, T. Kao, P.C. Doerschuk, and U. Wiesner, Self-assembly of highly symmetrical, ultrasmall inorganic cages directed by surfactant micelles. Nature, vol. 558, p. 577-+, 2018, doi: 10.1038/s41586-018-0221-0.
  38. K. Ma, K.A. Spoth, Y. Cong, D.H. Zhang, T. Aubert, M.Z. Turker, L.F. Kourkoutis, E. Mendes, and U. Wiesner, Early Formation Pathways of Surfactant Micelle Directed Ultrasmall Silica Ring and Cage Structures. Journal of the American Chemical Society, vol. 140, p. 17343-17348, 2018, doi: 10.1021/jacs.8b08802.
  39. J. Maes, L. Balcaen, E. Drijvers, Q. Zhao, J. De Roo, A. Vantomme, F. Vanhaecke, P. Geiregat, and Z. Hens, Light Absorption Coefficient of CsPbBr3 Perovskite Nanocrystals. Journal of Physical Chemistry Letters, vol. 9, p. 3093-3097, 2018, doi: 10.1021/acs.jpclett.8b01065.
  40. B. Martin-Garcia, D. Spirito, R. Krahne, and I. Moreels, Solution-processed silver sulphide nanocrystal film for resistive switching memories. Journal of Materials Chemistry C, vol. 6, p. 13128-13135, 2018, doi: 10.1039/c8tc04068k. 10
  41. M.E. Materia, M. Pernia Leal, M. Scotto, P.B. Balakrishnan, S. Kumar Avugadda, M.L. García-Martín, B.E. Cohen, E.M. Chan, and T. Pellegrino, Multifunctional Magnetic and Upconverting Nanobeads as Dual Modal Imaging Tools. Bioconjugate Chemistry, vol. 28, p. 2707-2714, 2017, doi: 10.1021/acs.bioconjchem.7b00432.
  42. M. Miscuglio, N.J. Borys, D. Spirito, B. Martin-Garcia, R.P. Zaccaria, A. Weber-Bargioni, P.J. Schuck, and R. Krahne, Planar Aperiodic Arrays as Metasurfaces for Optical Near-Field Patterning. Acs Nano, vol. 13, p. 5646-5654, 2019, doi: 10.1021/acsnano.9b00821.
  43. F. Palazon, G. Almeida, Q.A. Akkerman, L. De Trizio, Z.Y. Dang, M. Prato, and L. Manna, Changing the Dimensionality of Cesium Lead Bromide Nanocrystals by Reversible Postsynthesis Transformations with Amines. Chemistry of Materials, vol. 29, p. 4167-4171, 2017, doi: 10.1021/acs.chemmater.7b00895.
  44. F. Palazon, S. Dogan, S. Marras, F. Locardi, I. Nelli, P. Rastogi, M. Ferretti, M. Prato, R. Krahne, and L. Manna, From CsPbBr3 Nano-Inks to Sintered CsPbBr3-CsPb2Br5 Films via Thermal Annealing: Implications on Optoelectronic Properties. Journal of Physical Chemistry C, vol. 121, p. 11956-11961, 2017, doi: 10.1021/acs.jpcc.7b03389.
  45. F. Palazon, M. Prato, and L. Manna, Writing on Nanocrystals: Patterning Colloidal Inorganic Nanocrystal Films through Irradiation-Induced Chemical Transformations of Surface Ligands. Journal of the American Chemical Society, vol. 139, p. 13250-13259, 2017, doi: 10.1021/jacs.7b05888.
  46. M. Palei, V. Caligiuri, S. Kudera, and R. Krahne, Robust and Bright Photoluminescence from Colloidal Nanocrystal/Al2O3 Composite Films Fabricated by Atomic Layer Deposition. Acs Applied Materials & Interfaces, vol. 10, p. 22356-22362, 2018, doi: 10.1021/acsami.8b03769.
  47. S. Park, M.N. An, G. Almeida, F. Palazon, D. Spirito, R. Krahne, Z.Y. Dang, L. De Trizio, and L. Manna, CsPbX3/SiOx (X = Cl, Br, I) monoliths prepared via a novel sol-gel route starting from Cs4PbX6 nanocrystals. Nanoscale, vol. 11, p. 18739-18745, 2019, doi: 10.1039/c9nr07766a.
  48. U. Petralanda, L. De Trizio, G. Gariano, R. Cingolani, L. Manna, and S. Artyukhin, Triggering Cation Exchange Reactions by Doping. Journal of Physical Chemistry Letters, vol. 9, p. 4895-4900, 2018, doi: 10.1021/acs.jpclett.8b02083.
  49. A. Rossi, D. Spirito, F. Bianco, S. Forti, F. Fabbri, H. Buch, A. Tredicucci, R. Krahne, and C. Coletti, Patterned tungsten disulfide/graphene heterostructures for efficient multifunctional optoelectronic devices. Nanoscale, vol. 10, p. 4332-4338, 2018, doi: 10.1039/c7nr08703a.
  50. P. Schiettecatte, P. Geiregat, and Z. Hens, Ultrafast Carrier Dynamics in Few-Layer Colloidal Molybdenum Disulfide Probed by Broadband Transient Absorption Spectroscopy. Journal of Physical Chemistry C, vol. 123, p. 10571-10577, 2019, doi: 10.1021/acs.jpcc.9b01494.
  51. J. Shamsi, P. Rastogi, V. Caligiuri, A.L. Abdelhady, D. Spirito, L. Manna, and R. Krahne, Bright-Emitting Perovskite Films by Large-Scale Synthesis and Photoinduced Solid-State Transformation of CsPbBr3 Nanoplatelets. Acs Nano, vol. 11, p. 10206-10213, 2017, doi: 10.1021/acsnano.7b04761.
  52. Y. Tong, M. Fu, E. Bladt, H. Huang, A.F. Richter, K. Wang, P. Muller-Buschbaum, S. Bals, P. Tamarat, B. Lounis, J. Feldmann, and L. Polavarapu, Chemical Cutting of Perovskite Nanowires into Single-Photon Emissive Low-Aspect-Ratio CsPbX3 (X = Cl, Br, I) Nanorods. Angewandte Chemie-International Edition, vol. 57, p. 16094-16098, 2018, doi: 10.1002/anie.201810110.
  53. Y. Tong, E.P. Yao, A. Manzi, E. Bladt, K. Wang, M. Doblinger, S. Bals, P. Muller-Buschbaum, A.S. Urban, L. Polavarapu, and J. Feldmann, Spontaneous Self-Assembly of Perovskite Nanocrystals into Electronically Coupled Supercrystals: Toward Filling the Green Gap. Advanced Materials, vol. 30, 2018, doi: 10.1002/adma.201801117.
  54. J.Y. Wang, S. Choudhary, J. De Roo, K. De Keukeleere, I. Van Driessche, A.J. Crosby, and S.S. Nonnenmann, How Ligands Affect Resistive Switching in Solution-Processed HfO2 Nanoparticle Assemblies. Acs Applied Materials & Interfaces, vol. 10, p. 4824-4830, 2018, doi: 10.1021/acsami.7b17376. 11
  55. M.J. Wang, Z.Y. Dang, M. Prato, U. Petralanda, I. Infante, D.V. Shinde, L. De Trizio, and L. Manna, Ruthenium-Decorated Cobalt Selenide Nanocrystals for Hydrogen Evolution. Acs Applied Nano Materials, vol. 2, p. 5695-5703, 2019, doi: 10.1021/acsanm.9b01205.
  56. B.W. Zhang, L. Goldon, J. Zito, Z.Y. Dang, G. Almeida, F. Zaccaria, J. de Wit, I. Infante, L. De Trizio, and L. Manna, Alkyl Phosphonic Acids Deliver CsPbBr3 Nanocrystals with High Photoluminescence Quantum Yield and Truncated Octahedron Shape. Chemistry of Materials, vol. 31, p. 9140-9147, 2019, doi: 10.1021/acs.chemmater.9b03529.
  57. D. Zhou, J. Zito, V. Pinchetti, Z. Dang, A. Olivati, L. Pasquale, A. Tang, M. L. Zaffalon, F. Meinardi, I. Infante, L. De Trizio, L. Manna and S. Brovelli, Compositional Tuning of Carrier Dynamics in Cs2Na1−xAgxBiCl6 Double-Perovskite Nanocrystals. ACS Energy Letters, doi: 10.1021/acsenergylett.0c00914
  58. S. Toso, Q. A. Akkerman, B. Martìn- Garcìa, M. Prato, J. Zito, I. Infante, Z. Dang, A. Moliterni, C. Giannini, E. Bladt, I. Lobato, J. Ramade, S. Bals, J. Buha, D. Spirito, E. Mugnaioli, M. Gemmi and L. Manna, Nanocrystals of Lead Chalcohalides: A Series of Kinetically Trapped Metastable Nanostructures. Journal of the American Chemical Society, doi: 10.1021/jacs.0c03577